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Key technologies for harmlessness and resource utilization of waste household appliance composition materials
1. Waste CRT cone glass is harmless in a wet way, efficiently recovers high-value lead without secondary pollution. 2. waste liquid
Type
Regeneration technology
Tags
Information & systems
Electronic waste/by-product recycling
Material harmlessness
Solution maturity
Early adoption / Process verification
Cooperation methods
Face-to-face consultation
Applicable industry
Information transmission, software and information technology services
Applications
Resource utilization of electronic waste
Key innovations
These technologies achieve harmless and high-value waste through innovative methods such as hydrometallurgy, hydrothermal, solid fluidization, and ultrasonic cavitation. They have significant characteristics such as non-pollution, high efficiency, low cost, and high added value.
Potential economic benefits
Through the conversion of high value-added products, low cost, high recovery rate, no secondary pollution, and easy promotion, high-value utilization of resources is achieved and economic benefits are significantly improved.
Potential climate benefits
1. Wet method replaces pyrometallurgical lead smelting, reducing energy consumption and carbon emissions. Waste lead recycling reduces the extraction of primary resources and reduces the carbon footprint of mining and smelting. 2. Waste is recycled to avoid landfill emissions. Hydrothermal conversion to produce acetic acid replaces traditional routes and reduces fossil raw material consumption and energy consumption.
Solution supplier
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Tongji University
Tongji University
Tongji University: The national "double first-class" construction university uses advantageous disciplines such as civil engineering, architecture, transportation, and environment to cultivate innovative talents to serve national construction and sustainable urban development.
Shanghai,China
Solution details

1. Harmless and resource recycling technology for waste cathode ray tube display cone glass

Hydrometallurgical technology is used to convert lead in cone glass into lead sulfate, a high-value-added chemical product. This process does not produce secondary pollution. The whole process can realize closed circulation of waste liquid. Compared with pyrometallurgical lead smelting technology, the cost is low and the technology is simple, easy to promote, and the added value of the product is high.

2. Key technologies for harmlessness and resource utilization of waste LCD

Based on the remarkable characteristics of high temperature and high pressure water, waste liquid crystal hydrothermal oxidation technology and polarizer hydrothermal conversion technology to produce acetic acid have been developed respectively.

3. Key technologies for recycling waste printed circuit board materials

Based on the significant density difference between metals and nonmetals and the characteristics of solid fluidization, the developed solid fluidization airflow transportation separation and enrichment device and process can achieve efficient separation and enrichment of metals and nonmetals on the circuit board, and the entire process has no polluting emissions. After separation, the recovery rate of the main metal copper is as high as 96%, and the total metal recovery rate is as high as 95%.

4. Comprehensive treatment process for waste lithium batteries

For failed lithium cobaltate, based on the fact that the ultrasonic cavitation effect can provide conditions such as transient local high temperature, high pressure, and hydroxyl radicals with strong oxidizing ability for chemical reactions, the failed lithium cobaltate is treated in an ultrasonic cavitation environment under ultrasonic action. One-step impurity removal and repair research. The first discharge specific capacity of the repaired lithium cobalt oxide reaches 130 mAh/g, and the first charge and discharge efficiency is more than 98%.

Application situation or application prospectsThis project focuses on the toxic, harmful and valuable material components in used household appliances. With the help of the differences between the physical and chemical characteristics of these components, mechanical and physical methods are used to crush, dissociate, separate and enrich them, and hydrothermal technology, Pyrolysis technology, ultrasonic cavitation technology, etc. achieve harmlessness and high-value separation and enrichment components.


Last updated
01:01:04, Nov 08, 2025
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